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Gibbs free energy: the equation and the condition for feasibility

Dr Lavan Ganeshkumar, PhD · updated 4 October 2026

The Gibbs free energy change is given by delta G = delta H minus T delta S. A reaction is feasible when delta G is less than or equal to zero.

Words that must appear

  • Delta G less than or equal to zero
  • T

The sign

A negative delta G means the reaction is feasible. To find the temperature at which it just becomes feasible, set delta G to zero, so T equals delta H divided by delta S.

Do not confuse with

Enthalpy change alone. Gibbs free energy includes the entropy term and the temperature.

Common questions

What is the Gibbs free energy equation?

Delta G equals delta H minus T delta S.

When is a reaction feasible?

When delta G is less than or equal to zero.

Why might a feasible reaction not happen?

Feasibility says nothing about rate. A high activation energy can make it immeasurably slow.

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